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このアイテムの引用には次の識別子を使用してください: http://hdl.handle.net/10119/16247

タイトル: Optical Second Harmonic Generation Analysis of Unrubbed Polyimide Surfaces as a Function of the Content of Steroidal Structure Side Chains
著者: Nguyen, Trinh Thi
Yu, Sheng
Asakura, Shinya
Khuat, Thi Thu Hien
Mizutani, Goro
Murakami, Yoshitaka
Okada, Takashi
キーワード: Second harmonic generation
Polyimide
Polymer surface
Steroidal structure
発行日: 2020-05-02
出版者: The Japan Society of Vacuum and Surface Science
誌名: e-Journal of Surface Science and Nanotechnology
巻: 18
開始ページ: 175
終了ページ: 179
DOI: 10.1380/ejssnt.2020.175
抄録: Contribution of main chains and side chains of unrubbed polyimide films with steroidal structure side chains to second harmonic generation (SHG) response was studied by varying their molar fraction of side-chain diamine. The SHG intensity in P_<in>/P_<out> polarization (P-polarization input and P-polarization output) configuration does not depend strongly on the molar fraction. This indicates that both the main chains and side chains at the surface contribute similarly to the SHG intensity. The SHG intensity in S_<in>/P_<out> polarization configuration normalized by that of P_<in>/P_<out> polarization configuration was the smallest for the molar fraction of side-chain diamine of 0%. This fact indicates that the microscopic nonlinear dipoles are standing nearly upright at the surface of the film consisting only of the main chains, while their orientational spread is wider when the side chains are involved.
Rights: Nguyen Thi Trinh, Yu Sheng, Shinya Asakura, Khuat Thi Thu Hien, Goro Mizutani, Yoshitaka Murakami, Takashi Okada, e-Journal of Surface Science and Nanotechnology, 18, 2020, pp.175-179. DOI:10.1380/ejssnt.2020.175. All articles published on e-J. Surf. Sci. Nanotechnol. are licensed under the Creative Commons Attribution 4.0 International (CC BY 4.0). You are free to copy and redistribute articles in any medium or format and also free to remix, transform, and build upon articles for any purpose (including a commercial use) as long as you give appropriate credit to the original source and provide a link to the Creative Commons (CC) license. If you modify the material, you must indicate changes in a proper way.
URI: http://hdl.handle.net/10119/16247
資料タイプ: publisher
出現コレクション:c10-1. 雑誌掲載論文 (Journal Articles)

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