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http://hdl.handle.net/10119/16671
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| Title: | Proton Conductivity and Oriented Structure of Nafion Thin Films on the Au-Deposited Surface and MgO Substrate |
| Authors: | Nagao, Yuki
Enta, Aoi
Suwansoontorn, Athchaya
Ono, Yutaro |
| Issue Date: | 2018-12-13 |
| Publisher: | IOP Publishing |
| Magazine name: | ECS Transactions |
| Volume: | 88 |
| Number: | 1 |
| Start page: | 249 |
| End page: | 258 |
| DOI: | 10.1149/08801.0249ecst |
| Abstract: | In-plane proton conductivity and interfacial structure of Nafion thin films on the Au-deposited surface and MgO(100) substrate were investigated. Proton conductivity on both Au-deposited and MgO surfaces clearly decreased with decreasing the thickness except the conditions of 80% and 95% relative humidity on the Au-deposited surface. Proton conductivity drop on the MgO substrate was much heavier than that on the Au-deposited surface. Highly oriented structure was observed in both Nafion thin films on the Au-deposited surface and MgO surface by a p-polarized multiple angle incidence resolution spectrometry. While thickness dependent structural change was observed on the Au-deposited surface like the previous reported Nafion thin films on the Pt-deposited surface, thickness dependence of the structural change was not observed markedly on the MgO substrate. |
| Rights: | Copyright (C)2018 ECS. Yuki Nagao, Aoi Enta, Athchaya Suwansoontorn and Yutaro Ono, ECS Transactions, 88(1), 2018, pp.249-258. This is the Accepted Manuscript version of an article accepted for publication in ECS Transactions. The Electrochemical Society and IOP Publishing Ltd are not responsible for any errors or omissions in this version of the manuscript or any version derived from it. The Version of Record is available online at https://doi.org/10.1149/08801.0249ecst. |
| URI: | http://hdl.handle.net/10119/16671 |
| Material Type: | author |
| Appears in Collections: | c10-1. 雑誌掲載論文 (Journal Articles)
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