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http://hdl.handle.net/10119/17076
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| Title: | Imidazolium‐Functionalized Fluorene‐Based Anion Exchange Membrane (AEM) for Fuel Cell Applications |
| Authors: | Salma, Umme
Zhang, Dishen
Nagao, Yuki |
| Issue Date: | 2020-01-24 |
| Publisher: | Wiley-VCH |
| Magazine name: | Wiley ChemistrySelect |
| Volume: | 5 |
| Number: | 4 |
| Start page: | 1255 |
| End page: | 1263 |
| DOI: | 10.1002/slct.201903246 |
| Abstract: | After a fluorene-based anion exchange membrane (AEM) containing 1-isopropyl-2-methylimidazolium with alkyl side chains was prepared, the membrane properties, including OH– conductivities, ion exchange capacity (IEC), water uptake, swelling ratio, and chemical and thermal stabilities of the obtained membrane were assessed. The synthesized membrane exhibited low water uptake and good dimensional stability with adequate hydroxide conductivity. For example, the AEM showed a swelling ratio of 7% and hydroxide conductivity of 46 mS cm^<-1> at 80°C in liquid water. The chemical stability was investigated in 1 M NaOH solution at room temperature and at 80°C. At both temperatures, degradation of the imidazolium cationic groups was observed, although the main chain was chemically stable. All results obtained from this research are expected to provide important direction and insight for AEM synthesis for practical applications in anion exchange membrane fuel cells. |
| Rights: | This is the peer reviewed version of the following article: Copyright (C) 2020 Wiley-VCH. Umme Salma, Dishen Zhang, Yuki Nagao, Wiley ChemistrySelect, 5(4), 2020, pp.1255-1263, which has been published in final form at https://doi.org/10.1002/slct.201903246. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. |
| URI: | http://hdl.handle.net/10119/17076 |
| Material Type: | author |
| Appears in Collections: | c10-1. 雑誌掲載論文 (Journal Articles)
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