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Please use this identifier to cite or link to this item: http://hdl.handle.net/10119/19044

Title: One-Pot Synthesis of Furfural Derivatives from Pentoses using Solid Acid and Base Catalysts
Authors: Shirotori, Mahiro
Nishimura, Shun
Ebitani, Kohki
Issue Date: 2014-01-06
Publisher: Royal Society of Chemistry
Magazine name: Catalysis Science & Technology
Volume: 4
Number: 4
Start page: 971
End page: 978
DOI: 10.1039/C3CY00980G
Abstract: One-pot synthesis of (2-furanylmethylene)malononitrile, a Knoevenagel product of furfural with malononitrile, from xylose efficiently proceeded by combined use of acid Amberlyst-15 and acid-base Cr/hydrotalcites with 44% yield. Structural characterizations were carried out using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), X-ray absorption spectra, and nitrogen adsorption measurements. The Lewis acidic properties of a highly active Cr/HT were investigated using Meerwein-Ponndorf-Verley (MPV) reaction. It was confirmed that the prepared Cr/HT possessed the Lewis acid Cr2O3 on HT surface. Thus, the combined use of dispersed Lewis acid Cr2O3 and Brønsted base HT facilitated the isomerization step of aldose into ketose, and strongly promoted activity for the synthesis of furfural derivatives from aldoses through isomerization, dehydration and Knoevenagel condensation reactions in one-pot manner.
Rights: Copyright (C) 2014 Royal Society of Chemistry. Mahiro Shirotori, Shun Nishimura and Kohki Ebitani, Catalysis Science & Technology, 2014, 4(4), 971-978. https://doi.org/10.1039/C3CY00980G - Reproduced by permission of the Royal Society of Chemistry
URI: http://hdl.handle.net/10119/19044
Material Type: author
Appears in Collections:d10-1. 雑誌掲載論文 (Journal Articles)

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