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Please use this identifier to cite or link to this item: http://hdl.handle.net/10119/9188

Title: Spectral parameters and Hamaker constants of silicon hydride compounds and organic solvents
Authors: Masuda, Takashi
Matsuki, Yasuo
Shimoda, Tatsuya
Issue Date: 2009-08-21
Publisher: Elsevier
Magazine name: Journal of Colloid and Interface Science
Volume: 340
Number: 2
Start page: 298
End page: 305
DOI: 10.1016/j.jcis.2009.08.028
Abstract: Cyclopentasilane (CPS) and polydihydrosilane, which consist of hydrogen and silicon only, are unique materials that can be used to produce intrinsic silicon film in a liquid process, such as spin coating or an ink-jet method. Wettability and solubility of general organic solvents including the above can be estimated by Hamaker constants, which are calculated according to the Lifshitz theory. In order to calculate a Hamaker constant by the simple spectral method (SSM), it is necessary to obtain absorption frequency and function of oscillator strength in the ultraviolet region. In this report, these physical quantities were obtained by means of an optical method. As a result of examination of the relation between molecular structures and ultraviolet absorption frequencies, which were obtained from various liquid materials, it was concluded that ultraviolet absorption frequencies became smaller as electrons were delocalized. In particular, the absorption frequencies were found to be very small for CPS and polydihydrosilane due to σ-conjugate of their electrons. The Hamaker constants of CPS and polydihydrosilane were successfully calculated based on the obtained absorption frequency and function of oscillator strength.
Rights: NOTICE: This is the author's version of a work accepted for publication by Elsevier. Takashi Masuda, Yasuo Matsuki, Tatsuya Shimoda, Journal of Colloid and Interface Science, 340(2), 2009, 298-305, http://dx.doi.org/10.1016/j.jcis.2009.08.028
URI: http://hdl.handle.net/10119/9188
Material Type: author
Appears in Collections:c10-1. 雑誌掲載論文 (Journal Articles)

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