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このアイテムの引用には次の識別子を使用してください:
http://hdl.handle.net/10119/12087
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| タイトル: | Characterization, Synthesis and Catalysis of Hydrotalcite-related Materials for Highly Efficient Materials Transformations |
| 著者: | Nishimura, Shun
Takagaki, Atsushi
Ebitani, Kohki |
| キーワード: | hydrotalcite
characterization
synthesis
application for materials transformations |
| 発行日: | 2013-06-18 |
| 出版者: | Royal Society of Chemistry |
| 誌名: | Green Chemistry |
| 巻: | 15 |
| 号: | 8 |
| 開始ページ: | 2026 |
| 終了ページ: | 2042 |
| DOI: | 10.1039/C3GC40405F |
| 抄録: | This review is intended to introduce recent progresses in characterization, syntheses and catalysis of hydrotalcite (HT) and HT-related materials. NMR, in situ neutron diffraction and TG-DTA techniques have been used to determine local structure and structural changes of HT. Various synthetic methods to control morphology of HT are introduced together with the crystal formation mechanism. Preparation methods of magnetic HTs are also included. The HT acts as heterogeneous base catalyst for efficient transformations of organic compounds such as synthesis of glycerol carbonate, transesterification of oils (biodiesel production) and carbon-carbon bond formations. The HT has been also used as a support for immobilizing various metal species (Ru, Pd, Ag, Au, Pt, Cu, V, Mn…) which enables highly selective organic reactions such as dehydrogenation of alcohols and deoxygenation of epoxides. Cooperative actions between basic sites of the HT surface and supported metal species are introduced. It is also shown that the HT can work together with other solid acid and metal catalysts to promote sequential reactions in one-pot manner, which gives us very important methodology for environmentally-benign synthesis of value-added chemicals especially from biomass-derived compounds. |
| Rights: | Copyright (C) 2013 Royal Society of Chemistry. Shun Nishimura, Atsushi Takagaki, Kohki Ebitani, Green Chemistry, 15(8), 2013, 2026-2042. http://dx.doi.org/10.1039/C3GC40405F - Reproduced by permission of The Royal Society of Chemistry |
| URI: | http://hdl.handle.net/10119/12087 |
| 資料タイプ: | author |
| 出現コレクション: | c10-1. 雑誌掲載論文 (Journal Articles)
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このアイテムのファイル:
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| 19295.pdf | | 1322Kb | Adobe PDF | 見る/開く |
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