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Please use this identifier to cite or link to this item: http://hdl.handle.net/10119/12609

Title: MgO/MgCl_2/TiCl_4 Core-Shell Catalyst for Establishing Structure-Performance Relationship in Ziegler-Natta Olefin Polymerization
Authors: Chammingkwan, Patchanee
Thang, Vu Quoc
Terano, Minoru
Taniike, Toshiaki
Keywords: Ziegler-Natta polymerization
structure-performance relationship
core-shell
nanoparticle
α_S-plot
Issue Date: 2014-03-05
Publisher: Springer
Magazine name: Topics in Catalysis
Volume: 57
Number: 10-13
Start page: 911
End page: 917
DOI: 10.1007/s11244-014-0251-2
Abstract: Recently we successfully established the first structure-performance relationships between the catalyst surface area and propylene polymerization activity using novel MgO/MgC_l2/TiCl_4 core-shell catalysts with non-porous and non-fragmentable features. In the present paper, we have addressed the physical and chemical natures of these novel model catalysts in comparison with typical Ziegler-Natta catalysts, by means of comprehensive characterization and analyses. It was clarified that the MgO/MgCl_2/TiCl_4 core-shell catalysts offer an ideal and powerful tool to address relationships between the support architectures and polymerization performance, which had been long un-clarified.
Rights: This is the author-created version of Springer, Patchanee Chammingkwan, Vu Quoc Thang, Minoru Terano, ToshiakiTaniike, Topics in Catalysis, 57(10-13), 2014, 911-917. The original publication is available at www.springerlink.com, http://dx.doi.org/10.1007/s11244-014-0251-2
URI: http://hdl.handle.net/10119/12609
Material Type: author
Appears in Collections:c10-1. 雑誌掲載論文 (Journal Articles)

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