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Please use this identifier to cite or link to this item: https://hdl.handle.net/10119/18204

Title: Effects of passivation configuration and emitter surface doping concentration on polarization-type potential-induced degradation in n-type crystalline-silicon photovoltaic modules
Authors: Yamaguchi, Seira
Aken, Bas B. Van
Stodolny, Maciej K.
Löffler, Jochen
Masuda, Atsushi
Ohdaira, Keisuke
Keywords: Polarization-type potential-induced degradation
Photovoltaic module
n-type crystalline-silicon solar cell
Passivated emitter and rear totally diffused cell
Reliability
Acceleration test
Issue Date: 2021-03-31
Publisher: Elsevier
Magazine name: Solar Energy Materials and Solar Cells
Volume: 226
Start page: 111074
DOI: 10.1016/J.SOLMAT.2021.111074
Abstract: System voltages can cause significant degradation in photovoltaic modules. Polarization-type potential-induced degradation (PID) is accompanied by decreases in the short-circuit current density and the open-circuit voltage. The system voltage causes a polarization and surface charge accumulation, increasing the interface recombination. The surface passivation and the emitter doping concentration and gradient are considered to have large impacts. However, a systematic study on these effects has not yet been performed. In this paper, the effects of the front surface structure of n-type passivated emitter and rear totally diffused cell modules were investigated by accelerated PID tests. Standard cells with thin silicon dioxide/80 nm silicon nitride (SiN_x) antireflection/passivation layers, refractive index (RI) of 2.0, exhibited typical polarization-type PID. Cells with increased RI = 2.4 for the bottom 20 nm SiN_x showed no degradation at all. This may be caused by reduced charge accumulation in the SiN_x layer near the interface due to the higher electrical conductivity of the Si-rich bottom layer. Secondly, cells with both a highly distorted interface, due to nitrogen insertion in the silicon surface, and an emitter with a high surface doping concentration have excellent resistance to PID. Cells with either the highly distorted interface or the higher emitter-surface doping concentration show no to minor improved resistance to PID. These findings improve the understanding of the effects of the front surface structure of cells on the polarization-type PID and may contribute to the implementation of these measures to reduce PID.
Rights: Copyright (C)2021, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International license (CC BY-NC-ND 4.0). [http://creativecommons.org/licenses/by-nc-nd/4.0/]
URI: https://hdl.handle.net/10119/18204
Material Type: author
Appears in Collections:c10-1. 雑誌掲載論文 (Journal Articles)

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